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151.
152.
Recoveryofmolybdenum,phosphorusandarsenicfromleachingsolutionofmolybdenumresiduesbysolventextractionwithprimaryamineandtribut... 相似文献
153.
The big flood in the upper Elbe River catchment area has revealed a wide spectrum of problems with contaminated sediments. So far, an effective strategy for managing contaminated sediments on a river basin scale is still missing and it seems that not much has been learned from the lessons received during the last decade. In the following overview, special emphasis is given to the utilization of geochemically-based techniques for sediment remediation, which can be applied in different parts of a river basin. The examples presented here are mostly from the Elbe River catchment area. In general, new technical problem solutions need a set of practical process knowledge that uses a wide range of simulation techniques, as well as models in different spatial and temporal scales. The evaluation of recent flood events clearly demonstrates the importance of chemical expertise in the decision-making process for the sustainable development in river basins. 相似文献
154.
Robson R. M. Barizon Ricardo de Oliveira Figueiredo Débora Renata Cassoli de Souza Dutra Jussara Borges Regitano Vera Lúcia Ferracini 《Journal of environmental science and health. Part. B》2020,55(3):283-292
AbstractCamanducaia River is part of the Piracicaba watershed responsible for pumping water into the Cantareira System, which is one of the main water sources for the metropolis of São Paulo and Campinas, Brazil. Intensive use of pesticides and hilly topography represents a situation of high risk for river water contamination. Therefore, water samples from 12 locations were collected along the Camanducaia River and its tributaries, over a period of 4?mo during the rainy season, and analyzed by GC-MS/MS or UPLC- MS/MS for the presence of 46 pesticides. Seven pesticides (fipronil, methyl parathion, metolachlor, atrazine, carbofuran, diuron, and simazine) were positively detected. Only atrazine (the most frequently detected) and diuron were present at concentrations above the limit of quantification of the analytical method (0.32 and 0.57?μg L?1 for atrazine and diuron, respectively). Pesticides detection frequency was higher than expected for a river system where only 11.8% of the land area is under agriculture. The vulnerability of the Camanducaia basin to pesticide contamination is attributed to the high annual precipitation (> 1.5?m y?1 in the headwaters), associated with topographical features (steep terrain) and soil types that favor surface runoff, which has been exacerbated by poor soil management practices. 相似文献
155.
气相色谱法测定糙米中水胺硫磷和甲基异柳磷的残留量 总被引:3,自引:0,他引:3
本文用带氮磷检测器的气相色谱仪,测定糙米中水胺硫磷和甲基异柳磷残留量,结果表明:水胺硫磷和甲基异柳磷最小检出量分别为1.3×10~(-11)g和2.8×10~(-12)g,最低检出浓度分别为0.7ppb和0.1ppb,回收率添加浓度为0.05—5mg/kg时,回收率范围分别为89.9—97.8%和100.7—104.9%,变异系数绝对值分别为3.42—5.58%和1.33—2.36%。 相似文献
156.
157.
介质阻挡放电脱除模拟工业苯系物的可行性 总被引:1,自引:1,他引:0
采用介质阻挡放电(DBD)技术降解流动态"三苯"(苯、甲苯和二甲苯)模拟废气,分析了浓度、气体流速对其降解的影响.对混合"三苯"废气进行单级和串联运行中试放大试验研究,结果显示,DBD串联可以在一定程度上提高"三苯"的去除率.三级申联时三种气体去除率都达到89%以上,对"三苯"混合废气单位体积处理费用进行了估算,结果表明,单级运行时1000m3废气处理费用只需1~3元.最后指出,要真正实现DBD降解苯系物工业化,首先要解决的还是管壁结焦和出流气体中的气溶胶粒子问题. 相似文献
158.
The effect of 24-epibrassinolide seed soaking on imidacloprid residues in green pods and mature seeds of Brassica juncea L. plants was investigated. The activities of the antioxidative enzymes glutathione-S-transferase, glutathione peroxidase, glutathione reductase, ascorbate peroxidase and guaiacol peroxidase, and the content of glutathione were determined. Imidacloprid residues in green pods were analyzed and quantified by gas chromatography-mass spectrometry, revealing that 24-epibrassinolide treatment resulted in a decrease of residues by almost 30%. In mature seeds, no pesticide residues were detected. Activities of all the antioxidative enzymes and glutathione content were found to be high in plants grown in soil amended with 300 mg imidacloprid kg?1 soil, but pre-soaking with 100 nmol L?1 24-epibrassinolide further enhanced the activities of all these enzymes and the glutathione content. 相似文献
159.
Hai B. Wang Li R. Han Jun T. Feng 《Journal of environmental science and health. Part. B》2016,51(2):63-70
The effects of inoculants on the composting of Sophora flavescens residues were evaluated based on several physical, chemical and biological parameters, as well as the infrared spectra. Compared to the control compost without inoculants, the treatment compost with inoculants (Bacillus subtilis strain G-13 and Chaetomium thermophilum strain GF-1) had a significantly longer thermophilic duration, higher cellulase activity and a higher degradation rate of cellulose, hemicellulose and lignin (P < 0.05). Thus, a higher maturity degree of compost with apparently lower C:N ratio (15.88 vs. 17.77) and NH4-N:NO3-N ratio (0.16 vs. 0.20) was obtained with the inoculation comparing with the control (P < 0.05). Besides, the inoculants could markedly accelerate the composting process and increase the maturity degree of compost as indicated by the germination index (GI) in which the treatment reached the highest GI of 133.2% at day 15 while the control achieved the highest GI of 125.7% at day 30 of the composting. Inoculation with B. subtilis and C. thermophilum is a useful method to enhance the S. flavescens residues composting according to this study. 相似文献
160.
Dissipation of simultaneously applied insecticides alpha-cypermethrin and lambda-cyhalothrin was studied in a minor crop, aboveground part of white mustard (Sinapis alba L.). A validated gas chromatographic method (GC-ECD/NPD) was used to determine insecticide residues. Analytical performances were very satisfactory, with expanded uncertainties not higher than 14% (coverage factor k = 2, confidence level 95%). Dissipation of alpha-cypermethrin and lambda-cyhalothrin in white mustard followed first-order kinetics (R2 between 0.953 and 0.995), with half-lives of 3.1–4.6 and 2.9–3.7 days respectively. Based on the results of this two-year study and the relevant residue regulation, alpha-cypermethrin and lambda-cyhalothrin treatments can be considered safe for crop protection, feeding animals and the environment. 相似文献